A Zinc（II） Coordination Polymer Possessing a Linear Trinuclear Building Block [Zn3（CO2）6N2]

被引：0

作者：

蒋亚琪

李方方

谢兆雄

机构：

[1] Department of Chemistry and Key Laboratory for Physical Chemistry of Solid Surfaces College of Chemistry and Chemical Engineering

[2] Xiamen University

[3] Fujian 361005 China

来源：

Chinese Journal of Structural Chemistry | 2008年 / 03期

基金：

中国国家自然科学基金;

关键词：

zinc; coordination polymer; 4; 4’-bipyridine; 2’-biphenyldicarboxylic acid;

D O I：

10.14102/j.cnki.0254-5861.2008.03.004

中图分类号：

O631 [高分子物理和高分子物理化学];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new coordination polymer [Zn3(bpda)3(bpy)]1(H2bpda=2,2’-biphenyldicar-boxylic acid, bpy=4,4’-bipyridien) has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis, elemental analysis, TG analysis and IR spectrum. 1 Crystallizes in cubic crystal system, space group Ia3, with a=20.9687(9), V=9219.7(3)3, Z=8, and R(I> 2σ(I))=0.0431. Complex 1 is a three-dimensional framework involving a new building block, linear trinuclear {Zn3(CO2)6N2} cluster. In the structure, each bpda coordinates to four zinc atoms via its two bridging bidentate carboxylate groups. To the best of our knowledge, 1 implies a new coordination mode of 2,2’-biphenyldicarboxylic acid. The solid state fluorescent spectra show a strong emission peak at 451 nm (λex=341 nm).

引用

页码：267 / 272

页数：6

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