Diels-Alder Reactions of 3-Carboethoxy- and 3-Carbonitrile-2-Cyclohexen-1-one

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作者
Wen Qian YANG
Shi Zhi CHEN
Liang HUANG(Institute of Materia Medica
机构
关键词
Diels-Alder reaction; base-induced isomerization;
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O621 [有机化学一般性问题];
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摘要
Aluminum chloride induced Diels-Alder reactions of 3-carboethoxy- and 3-carbonitrile-2-cyclohexen-1-one with cyclopentadiene, isoprene and (E)-piperylene were described. Thestereochemistry of the adducts were confirmed by 2D-NMR spectroscopy and isomerizationreactions.
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页码:233 / 234
页数:2
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