Oxygen reduction on polycobaltprotoporphyrin film Ⅰ.Catalytic activity and stability of polycobaltprotoporphyrin film toward oxygen reduction

被引：0
|
作者：
WANG Bao-Chen XIAO Shao-Rong Changchun Institute of Applied Chemistry
机构：
来源：
ActaChimicaSinica(EnglishEdition) | 1989年 / 05期
关键词：
Co; rate; Catalytic activity and stability of polycobaltprotoporphyrin film toward oxygen reduction; Oxygen reduction on polycobaltprotoporphyrin film;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The catalytic activity of polycobaltprotoporphyrin(PCoPP)was compared with adsorbedcobaltprotoporphyrin monolayer.The results have shown that PCoPP film shows higher catalyticactivity and stability than monolayer on glass carbon electrode in both alkaline and acid solution.Catalytic activity of PCoPP goes through a maximum with increase of film thickness.A model wasproposed to explain such dependence.The effect of film thickness and solution pH on the stabilityof PCoPP film was studied.
引用
收藏
页码：385 / 392
页数：8
相关论文
共 50 条
  • [31] Kinetics of oxygen reduction on an epitaxial film of palladium on Pt(111)
    Climent, V
    Markovic, NM
    Ross, PN
    JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (14): : 3116 - 3120
  • [32] Oxygen reduction under a thin electrolyte film - Measurements of oxygen dissolution and diffusion rates -
    Yamazaki, T.
    Nishikata, A.
    Tsuru, T.
    Zairyo to Kankyo/ Corrosion Engineering, 2001, 50 (01): : 30 - 33
  • [33] Nafion Film-Templated Platinum Electrodes for Oxygen Reduction
    Sleightholme, Alice E. S.
    Wilkinson, David P.
    Bizzotto, Dan
    Ye, Siyu
    Gyenge, Elod L.
    ELECTROCATALYSIS, 2010, 1 (01) : 22 - 27
  • [34] Optimizing the Catalytic Activity of Pd-Based Multinary Alloys toward Oxygen Reduction Reaction
    Saidi, Wissam A.
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2022, 13 (04): : 1042 - 1048
  • [35] Pt-Pd catalytic nanoflowers: Synthesis, characterization, and the activity toward electrochemical oxygen reduction
    Tymen, Simon
    Undisz, Andreas
    Rettenmayr, Markus
    Ignaszak, Anna
    JOURNAL OF MATERIALS RESEARCH, 2015, 30 (15) : 2327 - 2339
  • [36] Preparation of nano-platinum and its catalytic activity toward methanol oxidation and oxygen reduction
    黄幼菊
    戴宏海
    李伟
    张庆龙
    赵灵智
    李伟善
    TransactionsofNonferrousMetalsSocietyofChina, 2007, (S1) : 1006 - 1009
  • [37] Unravelling catalytic activity trends in ceria surfaces toward the oxygen reduction and water oxidation reactions
    Lucchetti, Lanna E. B.
    Autreto, Pedro A. S.
    de Almeida, James M. M.
    Santos, Mauro C. C.
    Siahrostami, Samira
    REACTION CHEMISTRY & ENGINEERING, 2023, 8 (06) : 1285 - 1293
  • [38] Preparation of nano-platinum and its catalytic activity toward methanol oxidation and oxygen reduction
    Huang You-ju
    Dai Hong-hai
    Li Wei
    Zhang Qing-long
    Zhao Ling-zhi
    Li Wei-shan
    TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2007, 17 : S1006 - S1009
  • [39] Phosphorization Treatment Improves the Catalytic Activity and Durability of Platinum Catalysts toward Oxygen Reduction Reaction
    Guo, Ruiyun
    Bi, Wei
    Zhang, Ke
    Liu, Yaming
    Wang, Chaoqi
    Zheng, Yangzi
    Jin, Mingshang
    CHEMISTRY OF MATERIALS, 2019, 31 (19) : 8205 - 8211
  • [40] High Catalytic Activity of Carbon Supported PdCu Alloyed Catalysts toward Oxygen Reduction Reaction
    Gong, Q.
    Gong, S. P.
    Zheng, J. W.
    Cheng, X.
    Yang, W. F.
    Zhang, T. F.
    Huang, L. Y.
    SELECTED PROCEEDINGS FROM THE 233RD ECS MEETING, 2018, 85 (13): : 845 - 854
12345