Theoretical analysis of thermal/electric-filed poling silica glass

Based on the experimental results, three basic conclusions are summarized for the thermal/electric-field poling (TEFP) silica materials, with which the second-order nonlinear optical coefficient in the bulk silica glass after TEFP is calculated, and relationships between the coefficient and the applied voltage V0 in the poling process and the thickness of the nonlinear layer created from the poling are obtained. Theoretical results show that the second-order susceptibility x(2) and the second-harmonic efficiency η in the poled bulk glass are proportional to (?) and V02,respectively; x(2)-0.2-1.6 pm/v for the bulk glass after the typical TEFP; x(2) decreases with an increase in the poling time after the TEFP silica glass approximately reaches the steady state. Theoretical results are well consistent with the experimental reports.