Two N-donor Auxiliary Ligands Mediated Zn(Ⅱ) Coordination Polymers Incorporating 5-Nitro-1,2,3-benzenetricarboxylate Ligand: Syntheses, Crystal Structures, and Luminescent Properties

被引：0
|
作者：
张甜 [1 ]
赵一静 [1 ]
秦秋沛 [1 ]
机构：
[1] College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Functionoriented Porous Materials, Luoyang Normal University
来源：
ChineseJournalofStructuralChemistry | 2020年 / 39卷 / 06期
关键词：
coordination polymer; 5-nitro-1,2,3-benzenetricarboxylic acid; bis(imidazol-1-yl)methane; N-(4-pyridylmethyl)imidazole; photoluminescent properties;
D O I：
10.14102/j.cnki.0254-5861.2011-2547
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
摘要：
Two N-donor auxiliary ligands mediated Zn（Ⅱ） coordination polymers, namely, {[Zn（Hnbta）-（bimm）]（3H;O）};（1） and {[Zn;（nbta）(pyim)（H;O）]（2H;O）};（2）(H;nbta = 5-nitro-1,2,3-benzenetricarboxylic acid, bimm = bis（imidazol-1-yl）methane and pyim = N-（4-pyridylmethyl）imidazole), have been prepared by the hydrothermal reaction. Their structures were determined by single-crystal X-ray diffraction analysis, elemental analyses and infrared spectra. Compound 1 possesses a one-dimensional（1D） chain structure, while compound 2 features a two-dimensional（2D） network. In addition, they both exhibit high thermal stabilities and photoluminescent properties in the solid, and can be explored as potential luminescent materials.
引用
收藏
页码：1051 / 1056
页数：6
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