Palladium complex catalyzed rearrangement of allylic sulfinates

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作者：
LU Xi-Yan HUANG Yu-Jin Shanghai Institute of Organic Chemistry
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来源：
ActaChimicaSinica(EnglishEdition) | 1984年 / 02期
关键词：
Ph; Palladium complex catalyzed rearrangement of allylic sulfinates;
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摘要：
In a systematic study of the reactions between allylic esters of hetero-atom acids andlow valent transition metal complexes,we found that allylic sulfinates can easily rearrangeto the corresponding sulfones by the catalysis of Pd(PPh3)4.The reaction can be carriedout at lower temperature,in shorter time and with a higher yield than that of the correspondingthermal reaction.
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页码：185 / 187
页数：3
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