Heteropolymolybdate as a New Reaction-controlled Phase-transfer Catalyst for Efficient Alcohol Oxidation with Hydrogen Peroxide

被引：0
|
作者：
Zhi Huan WENG
机构：
来源：
ChineseChemicalLetters | 2006年 / 06期
关键词：
Heteropolymolybdate; reaction-controlled phase-transfer; alcohol; oxidation;
D O I：
暂无
中图分类号：
O643.32 [催化反应];
学科分类号：
摘要：
A new catalytic process for the synthesis of aldehyde from alcohol by oxidation with H2O2 with high selectivity was studied. In this system, heteropolymolybdate [C7H7N(CH3)3]3 {PO4[MoO(O2)2]4} was utilized as the reaction-controlled phase-transfer catalyst to catalyze oxidation of benzyl and aliphatic alcohols. The molar ratio of H2O2 and alcohol was 0.75, no other by-products were detected by gas chromatography, the results of oxidation reaction indicated that the catalyst has high activity and stability.
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页码：848 / 850
页数：3
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