GaI3 Catalyzed Tetrahydropyranylation of Alcohols and Phenols

被引：2
|
作者：
孙培培
胡志新
机构：
[1] College of Chemistry and Environmental Science
[2] Nanjing Normal University
[3] Jiangsu 210097
[4] China
来源：
Chinese Journal of Chemistry | 2004年 / 11期
关键词：
gallium triiodide; alcohol or phenol; 2-alkoxy(aryloxy)tetrahydropyran; the protection of hydroxyl group;
D O I：
暂无
中图分类号：
O643.3 [催化];
学科分类号：
081705 ;
摘要：
In dichloromethane, the nucleophilic addition of alcohols or phenols to 3,4-dihydro-2H-pyran (DHP) was cata-lyzed effectively by gallium triiodide which was generated in situ by the reaction of gallium metal and iodine to give the corresponding tetrahydropyranyl acetals in good to excellent yields.
引用
收藏
页码：1341 / 1343
页数：3
相关论文
共 50 条
  • [31] Zirconium sulfophenyl phosphonate as a heterogenous catalyst in tetrahydropyranylation of alcohols and phenols.
    Curini, M
    Epifano, F
    Marcotullio, MC
    Rosati, O
    Costantino, U
    TETRAHEDRON LETTERS, 1998, 39 (44) : 8159 - 8162
  • [32] A highly efficient and chemoselective synthetic protocol for tetrahydropyranylation/depyranylation of alcohols and phenols
    Khan, AT
    Mondal, E
    Borah, BM
    Ghosh, S
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2003, 2003 (21) : 4113 - 4117
  • [33] Tetrahydropyranylation of alcohols, thiols, phenols and primary amines catalysed by magnesium halide
    Goud, PM
    Goud, PS
    Reddy, KR
    Ashok, D
    JOURNAL OF CHEMICAL RESEARCH, 2003, (12) : 806 - 807
  • [34] Heterogeneous acidic catalysts for the tetrahydropyranylation of alcohols and phenols in green ethereal solvents
    Azzena, Ugo
    Carraro, Massimo
    Modugno, Gloria
    Pisano, Luisa
    Urtis, Luigi
    BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2018, 14 : 1655 - 1659
  • [35] SPANISH SEPIOLITE CLAY AS A NEW HETEROGENEOUS CATALYST FOR THE TETRAHYDROPYRANYLATION OF ALCOHOLS AND PHENOLS
    CAMPELO, JM
    GARCIA, A
    LAFONT, F
    LUNA, D
    MARINAS, JM
    SYNTHETIC COMMUNICATIONS, 1994, 24 (10) : 1345 - 1350
  • [36] Tetrahydropyranylation of Alcohols and Phenols Using Polystyrene Supported Lewis Acids as Catalysts
    Zhang Yi
    Dou Qianqian
    Liu Yuan
    Dai Liyan
    Wang Xiaozhong
    Chen Yingqi
    CHINESE JOURNAL OF CHEMISTRY, 2012, 30 (10) : 2567 - 2572
  • [37] Tetrahydropyranylation and depyranylation of alcohols catalyzed by aqueous zinc tetrafluoroborate
    Islam, S
    Majee, A
    Khan, AT
    SYNTHETIC COMMUNICATIONS, 2005, 35 (13) : 1789 - 1793
  • [38] A STRAIGHTFORWARD, EFFICIENT AND VERSATILE PREPARATION OF PROPARGYLIC ALCOHOLS FROM 1-ALKYNES AND ALDEHYDES VIA GAI3 AND AMINE
    HAN, Y
    HUANG, YZ
    TETRAHEDRON LETTERS, 1995, 36 (40) : 7277 - 7280
  • [39] Catalytic tetrahydropyranylation of phenols and alcohols using vanadium(V)-substituted polyoxomolybdates
    Gharib, Ali
    Jahangir, Manouchehr
    JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2012, 77 (03) : 287 - 296
  • [40] Graphite Oxide as an Efficient and Reusable Catalyst for Tetrahydropyranylation/Depyranylation of Alcohols and Phenols
    Xu, Liang
    Yang, Anwei
    Ma, Ning
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2013, 33 (09) : 2004 - 2009
12345