Effects of Emission Variability on Atmospheric CO2 Concentrations in Mainland China

Accurately assessing the impact of anthropogenic carbon dioxide (CO2) emissions on CO2 concentrations is essential for understanding regional climate change, particularly in high-emission countries like China. This study employed the GEOS-Chem chemical transport model to simulate and compare the spatiotemporal distributions of XCO2 of three anthropogenic CO2 emission inventories in mainland China for the 2018-2020 period and analyzed the effects of emission variations on atmospheric CO2 concentrations. In eastern China, particularly in the Yangtze River Delta (YRD) and Beijing-Tianjin-Hebei (BTH) regions, column-averaged dry air mole fractions of CO2 (XCO2) can exceed 420 ppm during peak periods, with emissions from these areas contributing significantly to the national total. The simulation results were validated by comparing them with OCO-2 satellite observations and ground-based monitoring data, showing that more than 70% of the monitoring stations exhibited a correlation coefficient greater than 0.7 between simulated and observed data. The average bias relative to satellite observations was less than 1 ppm, with the Emissions Database for Global Atmospheric Research (EDGAR) showing the highest degree of agreement with both satellite and ground-based observations. During the study period, anthropogenic CO2 emissions resulted in an increase in XCO2 exceeding 10 ppm, particularly in the North China Plain and the YRD. In scenarios where emissions from either the BTH or YRD regions were reduced by 50%, a corresponding decrease of 1 ppm in XCO2 was observed in the study area and its surrounding regions. These findings underscore the critical role of emission control policies in mitigating the rise in atmospheric CO2 concentrations in densely populated and industrialized areas. This research elucidates the impacts of variations in anthropogenic emissions on the spatiotemporal distribution of atmospheric CO2 and emphasizes the need for improved accuracy of CO2 emission inventories.