Reducing noble metal dependence: oxygen evolution reaction with a Ru-minimized Bi2Ru2O7@MOF-801 composite

被引:0
|
作者
Sujita, P. [1 ]
Gupta, Keshav [2 ]
Gopal, V. [1 ]
Sarmila, S. [1 ]
Vadivel, Sethumathavan [1 ]
机构
[1] SRM Inst Sci & Technol, Fac Engn & Technol, Dept Chem, Kattankulathur 603203, Tamil Nadu, India
[2] SRM Inst Sci & Technol, Fac Engn & Technol, Sch Comp, Dept Comp Technol CTECH, Kattankulathur 603203, Tamil Nadu, India
关键词
NANOPARTICLES; CATALYSTS;
D O I
10.1039/d4nr04140b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Developing efficient and noble metal-minimized electrocatalysts for the oxygen evolution reactions (OER) is critical for energy conversion reactions. Here we present Ru-minimized Bi2Ru2O7@MOF-801 that synergistically combines the high catalytic activity of the bimetallic oxide with the unique structural and hydrophilic properties of the Zr-MOF. The composite achieves superior OER performance with a low overpotential of 307 mV at 50 mA cm-2 and a Tafel slope of 99.8 mV dec-1 surpassing those of pure Bi2Ru2O7 and MOF-801. Comparative testing with cutting-edge catalysts shows that using less Ru and incorporating a MOF work well together, providing a promising way to make high-performance OER catalysts that are also cost-effective by integrating the MOF for energy applications.
引用
收藏
页码:3714 / 3720
页数:7
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