Fine-Tuning of the Sequential Self-Assembly of Entangled Polyhedra by Exploiting the Side-Chain Effect

被引：1
|
作者：
Domoto, Yuya [1 ]
Nakabayashi, Ren [1 ]
Tsurumi, Tasuki [1 ]
Yamamoto, Kidai [2 ]
Hayashi, Hironobu [3 ]
Nakamura, Yosuke [1 ]
Fujita, Makoto [2 ,4 ]
机构：
[1] Gunma Univ, Grad Sch Sci & Technol, Div Mol Sci, 1-5-1 Tenjin Cho, Kiryu, Gunma 3768515, Japan
[2] Univ Tokyo, Tokyo Coll, U Tokyo Inst Adv Study UTIAS, Mitsui Link Lab Kashiwanoha 1,FS CREATION, 6-6-2 Kashiwanoha, Kashiwa, Chiba 2770882, Japan
[3] Natl Inst Mat Sci NIMS, Ctr Basic Res Mat, 1-2-1 Sengen, Tsukuba, Ibaraki 3050047, Japan
[4] Natl Inst Nat Sci, Inst Mol Sci, Div Adv Mol Sci, 5-1 Higashiyama,Myodaiji Cho, Okazaki, Aichi 4448787, Japan
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2025年 / 20卷 / 06期
关键词：
Self-assembly; Entanglements; Coordination polyhedra; Interconversion; Acetylene; CAGES; COORDINATION; ARCHITECTURE; BINDING; KNOTS;
D O I：
10.1002/asia.202401378
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The control of the sequential self-assembly processes of highly entangled (Ag3L2)n (n=2,4,6,8) and Ag21L12 coordination polyhedra using side-chain effects was studied via the introduction of linear or branched side chains into the tripodal ligands. In addition to changes in the intermediate polyhedral species affording the multi- pathway process, disruption of the kinetic control of the sequential self-assembly was observed, thus demonstrating the utility of steric control for the construction of 3D-entangled molecular materials on the 5 nm scale with high molecular complexity.
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页数：6
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