Fine-Tuning of the Sequential Self-Assembly of Entangled Polyhedra by Exploiting the Side-Chain Effect

被引：1

作者：

Domoto, Yuya ^{[1
]}

Nakabayashi, Ren ^{[1
]}

Tsurumi, Tasuki ^{[1
]}

Yamamoto, Kidai ^{[2
]}

Hayashi, Hironobu ^{[3
]}

Nakamura, Yosuke ^{[1
]}

Fujita, Makoto ^{[2
,4
]}

机构：

[1] Gunma Univ, Grad Sch Sci & Technol, Div Mol Sci, 1-5-1 Tenjin Cho, Kiryu, Gunma 3768515, Japan

[2] Univ Tokyo, Tokyo Coll, U Tokyo Inst Adv Study UTIAS, Mitsui Link Lab Kashiwanoha 1,FS CREATION, 6-6-2 Kashiwanoha, Kashiwa, Chiba 2770882, Japan

[3] Natl Inst Mat Sci NIMS, Ctr Basic Res Mat, 1-2-1 Sengen, Tsukuba, Ibaraki 3050047, Japan

[4] Natl Inst Nat Sci, Inst Mol Sci, Div Adv Mol Sci, 5-1 Higashiyama,Myodaiji Cho, Okazaki, Aichi 4448787, Japan

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2025年 / 20卷 / 06期

关键词：

Self-assembly; Entanglements; Coordination polyhedra; Interconversion; Acetylene; CAGES; COORDINATION; ARCHITECTURE; BINDING; KNOTS;

D O I：

10.1002/asia.202401378

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The control of the sequential self-assembly processes of highly entangled (Ag3L2)n (n=2,4,6,8) and Ag21L12 coordination polyhedra using side-chain effects was studied via the introduction of linear or branched side chains into the tripodal ligands. In addition to changes in the intermediate polyhedral species affording the multi- pathway process, disruption of the kinetic control of the sequential self-assembly was observed, thus demonstrating the utility of steric control for the construction of 3D-entangled molecular materials on the 5 nm scale with high molecular complexity.

引用

页数：6

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