gas sensing;
CeO2;
n-butanol;
oxygen vacancies;
LOW-TEMPERATURE;
SENSOR;
D O I:
10.3390/s25041208
中图分类号:
O65 [分析化学];
学科分类号:
070302 ;
081704 ;
摘要:
The Cr-doped CeO2 nanomaterials were prepared by a simple hydrothermal method. Morphological analysis revealed that Cr doping altered the morphology and size of the CeO2 particles. Gas sensing tests results showed that Cr/Ce-2 has the highest response (R-a/R-g = 15.6 @ 10 ppm), which was 12.58 times higher than that of the pure CeO2 sensor. Furthermore, the optimal operating temperature was reduced from 210 degrees C to 170 degrees C. The Cr/Ce-2 sensor also displayed outstanding repeatability and gas selectivity. The improved gas sensing performance of the Cr-doped CeO2 sensor can be attributed to its smaller grain size and higher porosity compared to pure CeO2. In addition, oxygen vacancies played a pivotal role in improving the gas-sensing performance. The present work provides a new CeO2-based gas-sensitive material for the detection of n-butanol.
机构:
Kongunadu Arts & Sci Coll, Dept Phys, Coimbatore 641029, Tamil Nadu, IndiaKongunadu Arts & Sci Coll, Dept Phys, Coimbatore 641029, Tamil Nadu, India
Veena, B.
Pavithra, S.
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Karunya Inst Technol & Sci, Dept Appl Phys, Coimbatore 641114, Tamil Nadu, IndiaKongunadu Arts & Sci Coll, Dept Phys, Coimbatore 641029, Tamil Nadu, India
Pavithra, S.
Seetha, M.
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Kongunadu Arts & Sci Coll, Dept Phys, Coimbatore 641029, Tamil Nadu, IndiaKongunadu Arts & Sci Coll, Dept Phys, Coimbatore 641029, Tamil Nadu, India
Seetha, M.
Sakunthala, A.
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Karunya Inst Technol & Sci, Dept Appl Phys, Coimbatore 641114, Tamil Nadu, IndiaKongunadu Arts & Sci Coll, Dept Phys, Coimbatore 641029, Tamil Nadu, India
Sakunthala, A.
Masuda, Yoshitake
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机构:
Natl Inst Adv Ind Sci & Technol, Electroceram Grp, IFMRI, Moriyama Ku, Nagoya, JapanKongunadu Arts & Sci Coll, Dept Phys, Coimbatore 641029, Tamil Nadu, India