Pathway Selectivity in 2D Electronic-Vibrational Spectroscopy with Quantum Light

被引：0
|
作者：
Jadoun, Deependra [1 ,2 ]
Yadalam, Hari K. [1 ,2 ]
Harbola, Upendra [3 ]
Chernyak, Vladimir Y. [4 ,5 ]
Kizmann, Matthias [1 ,2 ]
Mukamel, Shaul [1 ,2 ]
机构：
[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92614 USA
[2] Univ Calif Irvine, Dept Phys & Astron, Irvine, CA 92614 USA
[3] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, India
[4] Wayne State Univ, Dept Chem, 5101 Cass Ave, Detroit, MI 48202 USA
[5] Wayne State Univ, Dept Math, 656 W Kirby, Detroit, MI 48202 USA
来源：
LASER & PHOTONICS REVIEWS | 2025年
基金：
美国国家科学基金会;
关键词：
2D spectroscopy; electronic-vibrational spectroscopy; entangled photons; HARVESTING COMPLEX; CRYSTAL-STRUCTURE; EXCITATION;
D O I：
10.1002/lpor.202401576
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
Pathway selectivity in quantum spectroscopy with entangled photons is a powerful spectroscopic tool. Phase-matched signals involving classical light contain contributions from multiple material pathways, whereas quantum spectroscopy may allow the selection of individual pathways. 2D electronic-vibrational spectroscopy (2DEVS) is a four-wave mixing technique which employs visible and infrared entangled photons. It is showed how the three contributing pathways-ground state bleach, excited state absorption, and excited state emission-can be separated by photon-number-resolved coincidence measurements. Entangled photons thus reveal spectral features not visible in the classical signal, with an enhanced spectral resolution.
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页数：8
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