Different effects of polyphenols on hydration, pasting and rheological properties of rice starch under extrusion condition: From the alterations in starch structure

Effects of polyphenols including caffeic acid (CA), ferulic acid (FA), epigallocatechin gallate (EG), tannic acid (TA) and resveratrol (R) on physicochemical and structural properties of rice starch (RS) under the extrusion condition were investigated. Extrusion altered the hydration, pasting and rheological properties of rice starch. Adding FA exhibited the best improvement effect on hydration properties of extruded rice starch (E-RS). All polyphenols possessed different inhibitory effects on short-term retrogradation of E-RS following the order of TA > EG > CA > FA > R. The FA and CA enhanced the viscoelasticity of E-RS, whereas the other polyphenols had opposite influences. Polyphenols mainly interacted with starch via hydrogen bonds, which transformed the crystalline structure to V-type and increased the molecular weight of E-RS. Above different effects were due to polyphenols exhibited varied microstructure and phenolic hydroxyl group content. These findings provided valuable information for preparing extruded starchy foods rich in polyphenols.