Visible light-induced radical cascade hydroaminoalkylation involving two distinct alkenes

This paper describes a visible-light-mediated three-component dicarbofunctionalization of alkenes via a tandem radical addition reaction of two different alkenes triggered by aminoalkyl radicals derived from N-phenyl glycines. This method allows for one-pot skeletal assembly, providing efficient and straightforward access to structurally complex gamma-amino sulfone derivatives directly from readily available and simple starting materials. Beyond the convenience of the one-pot protocol, this method also demonstrates broad substrate scope, excellent functional group compatibility, mild reaction conditions, and ease of scalability.