Preparation of Carbon Dots with High Fluorescence Quantum Yields and its Detection of Hg2+ in Simulated Wastewater

Fluorescent carbon quantum dots (CDs) have received widespread attention for their potential applications in optical sensing. Meanwhile, as the importance of mercury ion (Hg2+) detection in the environment, the exploration of Hg2+ fluorescent nanosensor based on CDs with high quantum yield is particularly intriguing. Herein, nitrogen-doped carbon quantum dots (N-CDs) were prepared by microwave method using citric acid as carbon source and urea as nitrogen source, and glycerol as microwave solvent. The N-CDs were characterized by transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) technique, Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). The fluorescence quantum yield of the N-CDs is calculated to be as high as 60.51%. The N-CDs can specifically recognize Hg2+, and there exists a strong linear correlation between the concentration of Hg2+ and the fluorescence quenching intensity of N-CDs. The linear equation is F0/F = 0.0062c + 1.5532, R2 = 0.9936, and the detection limit is 0.080 mu mol/L. The experimental results show that the recovery rate of Hg2+ in simulated wastewater ranges from 97 to 102%, and the relative standard deviation (RSD) is less than 3%, indicating that the prepared N-CDs can be used as a fluorescent probe for accurate detection of Hg2+.