Copper-Catalyzed Ring-Opening Hydrosilylation and Hydroboration of Arylidenecyclopropanes

被引：0
|
作者：
Xiao, Zhen-Yu [1 ]
Wang, Zi-Lu [1 ]
Xu, Yun-He [1 ]
机构：
[1] Univ Sci & Technol China, Dept Chem, 96 Jinzhai Rd, Hefei 230026, Anhui, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2025年 / 43卷 / 04期
基金：
中国国家自然科学基金;
关键词：
Hydrosilylation; Hydroboration; Copper catalysis; Arylidenecyclopropanes; ALLYLIC SUBSTITUTION; VINYLCYCLOPROPANES; METHYLENECYCLOPROPANES; 1,2-HYDROBORATION; SILABORATION; DERIVATIVES; SELECTIVITY; ALLYLATION; ACTIVATION; 1,3-DIENES;
D O I：
10.1002/cjoc.202400811
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Arylidenecyclopropanes (ACPs) are highly strained substrates that can be readily utilized for diverse transformations. This study showcases the outcomes of copper-catalyzed ring-opening hydrosilylation and hydroboration reactions of ACPs, showcasing precise cleavage of C-C bonds. The reaction presents an effective and convenient method for producing homoallylic silanes and boronates.
引用
收藏
页码：385 / 392
页数：8
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