Highly efficient low-valence tungsten-catalyzed deoxygenative reduction of tertiary amides to amines with pinacolborane

被引：0
|
作者：
Cheng, Biao [1 ]
Xv, Jialong [1 ]
Ren, Xiang [2 ]
Li, Yuanyuan [1 ]
Ji, Xiaoming [1 ]
Lu, Zhan [2 ]
机构：
[1] Henan Agr Univ, Coll Tobacco Sci, Flavors & Fragrance Engn & Technol Res Ctr Henan P, Zhengzhou 450046, Peoples R China
[2] Zhejiang Univ, Dept Chem, Hangzhou 310058, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2025年
基金：
中国国家自然科学基金;
关键词：
HYDROBORATION REDUCTION; DECATUNGSTATE ANION; SECONDARY AMIDES; HYDROGENATION; COMPLEXES; PHOTOCHEMISTRY; SELECTIVITY; MOLYBDENUM; CHEMISTRY; CARBON;
D O I：
10.1039/d4qo02340d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A highly efficient low-valence tungsten-catalyzed deoxygenative reduction of tertiary amides to amines with pinacolborane (HBPin) is developed. This protocol uses commercially available W(CO)6 as a catalyst in a solution of hexane under the irradiation of visible light without other additives, and the TON is up to 2000.
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页数：7
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