Driving Feringa Motors with Visible Light by Intermolecular Singlet Energy Transfer from a Commercial [Ru(bpy)3]2+ Photosensitizer

被引:0
|
作者
Luo, Cheng [1 ]
Liao, Guohong [2 ,4 ]
Jiang, Ziwei [1 ]
Zhang, Chen [1 ]
Liu, Bin [1 ]
Liu, Li [2 ]
Luo, Yanling [3 ]
Li, Quan [3 ]
机构
[1] Hubei Univ, Coll Chem & Chem Engn, Collaborat Innovat Ctr Adv Organ Chem Mat Coconstr, Minist Of Educ,Key Lab Synth & Applicat Organ Func, Wuhan 430062, Peoples R China
[2] Chinese Acad Sci, Inst Phys, Lab Soft Matter Phys, Beijing 100190, Peoples R China
[3] Tianjin Univ Tradit Chinese Med, Sch Chinese Mat Med, Tianjin Key Lab Therapeut Subst Tradit Chinese Med, Tianjin 301617, Peoples R China
[4] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
MOLECULAR MOTORS; UNIDIRECTIONAL ROTATION; DRIVEN; NANOMACHINES; MOTION; ROTOR;
D O I
10.1021/acs.orglett.5c00490
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
We herein report that a commercialized photosensitizer, Ru(bpy)3Cl2, can be successfully employed to "uphill" drive the rotation of Feringa motors via a singlet rather than an intuitive triplet intermolecular energy transfer mechanism, offering new insights into the sensitization strategy to power Feringa motors with more biocompatible light sources.
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页数:5
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