Ruthenium(II)-Catalyzed C-H Allylation of N , N -Dialkylthiobenzamides with Allyl Methyl Carbonate by Sulfur Coordination

被引：0
|
作者：
Wang, Runbao [1 ]
Jin, Kun [1 ]
Zhang, Rong [1 ]
Li, Yaming [1 ]
Duan, Chunying [1 ]
Zhao, Liang [1 ]
机构：
[1] Dalian Univ Technol, Frontier Sci Ctr Smart Mat, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China
来源：
SYNLETT | 2024年
基金：
中国国家自然科学基金;
关键词：
C-H bond activation; directing group; ruthenium catalysis; allylation; thiobenzamides;
D O I：
10.1055/a-2415-3708
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This report describes a Ru(II)-catalyzed C-H allylation of N , N -dialkylthiobenzamides with allyl methyl carbonate. The reaction is carried out using [RuCl2 (p-cymene)](2 )in the presence of Cu(OAc)(2) and Ag2O. This method represents the first example of a Ru-catalyzed C-H allylation directed by a sulfur-containing group. As a further advantage, the method is performed in sustainable and ecofriendly MeCN as the solvent.
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页数：4
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