Ruthenium(II)-Catalyzed C-H Allylation of N , N -Dialkylthiobenzamides with Allyl Methyl Carbonate by Sulfur Coordination

被引：0

作者：

Wang, Runbao ^{[1
]}

Jin, Kun ^{[1
]}

Zhang, Rong ^{[1
]}

Li, Yaming ^{[1
]}

Duan, Chunying ^{[1
]}

Zhao, Liang ^{[1
]}

机构：

[1] Dalian Univ Technol, Frontier Sci Ctr Smart Mat, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China

来源：

SYNLETT | 2024年

基金：

中国国家自然科学基金;

关键词：

C-H bond activation; directing group; ruthenium catalysis; allylation; thiobenzamides;

D O I：

10.1055/a-2415-3708

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This report describes a Ru(II)-catalyzed C-H allylation of N , N -dialkylthiobenzamides with allyl methyl carbonate. The reaction is carried out using [RuCl2 (p-cymene)](2 )in the presence of Cu(OAc)(2) and Ag2O. This method represents the first example of a Ru-catalyzed C-H allylation directed by a sulfur-containing group. As a further advantage, the method is performed in sustainable and ecofriendly MeCN as the solvent.

引用

页数：4

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