Microwave dielectric properties of Na2O-Ln2O3-MoO3-TiO2 (Ln = Nd, La and Ce) system with low-sintering temperature

被引:0
|
作者
Li, Wen-Bo [1 ]
Pang, Li-Xia [1 ]
Wang, Xiao-Long [1 ]
Liu, Wei-Guo [1 ]
Yao, Xiaogang [2 ]
Lin, Huixing [2 ]
Liu, Wen-Feng [3 ]
Zhou, Di [4 ]
机构
[1] Xian Technol Univ, Lab Thin Film Tech & Opt Test, Xian 710032, Shaanxi, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Inorgan Funct Mat & Device, Shanghai, Peoples R China
[3] Xi An Jiao Tong Univ, State Key Lab Elect Insulat & Power Equipment, Xian, Shaanxi, Peoples R China
[4] Xi An Jiao Tong Univ, Sch Elect Sci & Engn, Key Lab Multifunct Mat & Struct, Minist Educ, Xian 710049, Shaanxi, Peoples R China
基金
中国国家自然科学基金;
关键词
La and Ce ceramics; LTCC; microwave dielectric properties; Na2O-Ln(2)O(3)-MoO3-TiO2 (Ln = Nd); temperature coefficient of resonant frequency; PHASE EVOLUTION; CRYSTAL-STRUCTURE; SCHEELITE; CERAMICS; BIVO4; CA;
D O I
10.1111/ijac.14983
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
This study examines the low-loss and temperature-stable Na2O-Ln(2)O(3)-MoO3-TiO2 (Ln = Nd, La and Ce) system, synthesized via a solid-state process at low-sintering temperatures ranging from 840 degrees C to 900 degrees C The structure, microstructure and microwave properties of the Na(0.5)Ln(0.5)MoO(4)-TiO2 (Ln = Nd, La and Ce) ceramics as a function of the sintering temperature were studied. The results of XRD patterns and microstructure characterization showed that the main phase in compositions belong to tetragonal scheelite and tetragonal structure. The ceramic composition Na(0.5)Ln(0.5)MoO(4)-TiO2 (Ln = Nd, La and Ce), sintered at 840 degrees C-900 degrees C for 2 hours, demonstrated excellent microwave dielectric properties, exhibiting relative dielectric constant (epsilon(r)) of 13.9-14.4, Q x f value of about 31 100 (at 9.66 GHz) - 48 600 GHz (at 9.33 GHz), and temperature coefficient of -8.1 to -1 ppm/degrees C. Our work designs temperature-stable microwave dielectric ceramics with low-sintering temperature for LTCC technology applications.
引用
收藏
页数:8
相关论文
共 50 条
  • [31] THE SYSTEMS LN2O3-V2O5-NB2O5 (LN=CE, PR, ND, SM, EU)
    ZUEV, MG
    FOTIEV, AA
    INORGANIC MATERIALS, 1988, 24 (12) : 1754 - 1756
  • [32] Research Progress of BaO-Ln2O3-TiO2 System Microwave Dielectric Ceramics with High Permittivity and Low Loss
    Wang G.
    Fu Q.
    Zhang L.
    Shi H.
    Tian F.
    Cailiao Daobao/Materials Reports, 2019, 33 (07): : 2151 - 2158
  • [33] FLUORITE-RELATED LN2MO2O7 OXIDES IN THE LN2O3-MOO2 SYSTEM
    MANTHIRAM, A
    GOPALAKRISHNAN, J
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1980, 19 (11): : 1042 - 1045
  • [34] SYSTEMS LN2O2S-SB2S3 (LN-LA, CE, PR)
    ALIEV, OM
    TANRYVERDIEV, VS
    ALIEV, II
    INORGANIC MATERIALS, 1993, 29 (04) : 546 - 549
  • [35] Electronic properties of La3Ni2O7 and Ln4Ni3O10, Ln = La, Pr and Nd
    Rutgers The State Univ of New Jersey, Piscataway, United States
    Synth Met, 1-3 (1451-1452):
  • [36] Microwave Dielectric Properties of Temperature-Stable BaLn2(MoO4)4-TiO2 (Ln = Ce, Nd, and Sm) Ceramics
    Li, Wen-Bo
    Xi, Hai-Hong
    Zhou, Di
    JOURNAL OF ELECTRONIC MATERIALS, 2015, 44 (11) : 4250 - 4254
  • [37] Microwave Dielectric Properties of Temperature-Stable BaLn2(MoO4)4–TiO2 (Ln = Ce, Nd, and Sm) Ceramics
    Wen-Bo Li
    Hai-Hong Xi
    Di Zhou
    Journal of Electronic Materials, 2015, 44 : 4250 - 4254
  • [38] Correlation between structures and ionic conductivities of Na(2)Ln(2)Ti(3)O(10) (Ln=La, Nd, Sm, and Gd)
    Park, K
    Byeon, SH
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1996, 17 (02) : 168 - 172
  • [39] Microstructure and electrical properties of Ln2Ti2O7 (Ln = La, Nd)
    Kim, WS
    Ha, SM
    Yun, S
    Park, HH
    THIN SOLID FILMS, 2002, 420 : 575 - 578
  • [40] Structure and dielectric properties of BaO-TiO2-Nd2O3-La2 O3 ceramic system
    Zhang, H.
    Xie, D.H.
    Xiang, Y.
    Wang, H.R.
    Zhang, Z.P.
    Dianzi Keji Daxue Xuebao/Journal of University of Electronic Science and Technology of China, 2001, 30 (04):