Synthesis, Optical and Electrical Properties of High-Entropy Niobate (Mg0.2Cu0.2Ni0.2Co0.2Zn0.2)Nb2O6 with a Columbite Structure

被引：0
|
作者：
Koroleva, M. S. [1 ]
Maksimov, V. S. [1 ,2 ]
Piir, I. V. [1 ]
机构：
[1] Russian Acad Sci, FRC Komi Sci Ctr, Inst Chem, Ural Branch, Syktyvkar 167000, Russia
[2] Pitirim Sorokin Syktyvkar Univ, Syktyvkar 167005, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2024年 / 69卷 / 10期
关键词：
high-entropy columbite; band gap; conductivity; MICROWAVE DIELECTRIC-PROPERTIES; HYDROTHERMAL SYNTHESIS; OXIDE; MN; SUBSTITUTION; CERAMICS; M2+NB2O6; CONB2O6; CATHODE; CUNB2O6;
D O I：
10.1134/S0036023624602198
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The high-entropy niobate (Mg0.2Cu0.2Ni0.2Co0.2Zn0.2)Nb2O6 with a columbite structure has been synthesized for the first time by a modified solution combustion method followed by high-temperature sintering. According to the diffuse reflectance spectra, the direct band gap is 3.36 eV. The niobate is characterized by the mixed electronic-ionic conductivity (2.5 x 10(-3) S/cm at 750 degrees C) comparable with the conductivity of columbite Mg0.8Cu0.2Nb2O6.
引用
收藏
页码：1487 / 1492
页数：6
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