Direct oxidative esterification;
Esterification of benzaldehydes;
Esterification of benzylalcohols;
Perchlorate ionic liquid;
Task-specific ionic liquid;
AEROBIC OXIDATION;
DERIVATIVES;
ALDEHYDES;
EFFICIENT;
FACILE;
ACIDS;
D O I:
10.1007/s13738-024-03121-8
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Imidazolium perchlorate task-specific ionic liquids (TSILs) were used for in-situ oxidation esterification of benzaldehydes and benzylalcohols in reaction with alcohols. CO2H functional group containing TSIL show dual role as catalyst and reaction media toward oxidative esterifications. Excellent yields of esters could be obtained for a series of benzaldehydes and benzylalcohols via the reaction with alcohols. This reaction can be regarded as a new method for the efficient oxidation esterification of benzaldehydes and benzylalcohols under mild catalyst and solvent-free conditions.
机构:
Indira Gandhi Ctr Atom Res, Div Fuel Chem, Kalpakkam 603102, Tamil Nadu, IndiaIndira Gandhi Ctr Atom Res, Div Fuel Chem, Kalpakkam 603102, Tamil Nadu, India
Rout, A.
Venkatesan, K. A.
论文数: 0引用数: 0
h-index: 0
机构:
Indira Gandhi Ctr Atom Res, Div Fuel Chem, Kalpakkam 603102, Tamil Nadu, IndiaIndira Gandhi Ctr Atom Res, Div Fuel Chem, Kalpakkam 603102, Tamil Nadu, India
Venkatesan, K. A.
Srinivasan, T. G.
论文数: 0引用数: 0
h-index: 0
机构:
Indira Gandhi Ctr Atom Res, Div Fuel Chem, Kalpakkam 603102, Tamil Nadu, IndiaIndira Gandhi Ctr Atom Res, Div Fuel Chem, Kalpakkam 603102, Tamil Nadu, India
Srinivasan, T. G.
Rao, P. R. Vasudeva
论文数: 0引用数: 0
h-index: 0
机构:
Indira Gandhi Ctr Atom Res, Div Fuel Chem, Kalpakkam 603102, Tamil Nadu, IndiaIndira Gandhi Ctr Atom Res, Div Fuel Chem, Kalpakkam 603102, Tamil Nadu, India