Novel molybdenum sulfide-decorated graphitic carbon nitride nanohybrid for enhanced electrochemical oxygen evolution reaction

被引:1
|
作者
Fatima, Arooj [1 ]
Alrowaily, Albandari W. [2 ]
Alyousef, Haifa A. [2 ]
Alotaibi, B. M. [2 ]
Dahshan, A. [3 ]
机构
[1] Govt Grad Coll, Dept Chem, Taunsa Sharif 32100, Pakistan
[2] Princess Nourah Bint Abdulrahman Univ, Coll Sci, Dept Phys, POB 84428, Riyadh 11671, Saudi Arabia
[3] King Khalid Univ, Coll Sci, Dept Phys, Abha 61413, Saudi Arabia
关键词
Molybdenum sulfide; MoS2; g-CN composite; Hydrothermal method; Alkaline media; Oxygen evolution reaction; MOS2; ELECTROCATALYST; PERFORMANCE; G-C3N4; HYBRID;
D O I
10.1007/s10971-024-06561-z
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Transition metal chalcogenides are potentially better than electrocatalysts for the OER electrolysis that contain rare earth metals. Still, they have not yet developed to a catalytic performance level that would enable widespread adoption. To attain high-efficiency OER, it is imperative to create logical designs for electrocatalysts based upon transition metals on showing polymer substrate. Here, we discuss the sonication fabrication and extraordinary catalytic activity of MoS2/g-CN in alkaline media as an OER electrocatalyst. Various techniques like X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) and scanning electron microscopy (SEM) are employed to evaluate the structure, surface characteristics and morphology. Conversely, the MoS2/g-CN electrode's higher specific SA, outstanding conductivity and very porous framework in 1M alkaline KOH led to superior OER campaign (overpotential 203mV with Tafel slope 36mV/dec). It showed increased OER activity by maintaining high stability for about 35h. Our results suggest that graphitic carbon nitride can produce steady and sustainable energy and that transition metal chalcogenides with specific morphologies can improve electrocatalytic efficacy. Because of the distinct crystal phase-linked electrical properties, this discovery provides a fresh perspective for potential applications. [Graphical Abstract]
引用
收藏
页码:776 / 789
页数:14
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