Palladium-catalyzed hydrocarbonylative cross-coupling with two different alkenes

被引：0
|
作者：
Chen, Yi [1 ,2 ]
Wu, Jianing [1 ,2 ]
Ding, Yongzheng [3 ,4 ]
Huang, Hanmin [1 ,2 ]
机构：
[1] Univ Sci & Technol China, Key Lab Precis & Intelligent Chem, Hefei 230026, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
[3] Univ Sci & Technol China, Hefei Natl Res Ctr Phys Sci Microscale, Hefei 230026, Peoples R China
[4] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2024年 / 12卷 / 01期
基金：
国家重点研发计划; 中国国家自然科学基金;
关键词：
CARBONYLATIVE CYCLOADDITION; AMINOCARBONYLATION;
D O I：
10.1039/d4qo01312c
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Transition metal-catalyzed hydrocarbonylation of alkenes has been widely studied; however, the hydrocarbonylation reaction that took place between two alkenes has been largely unexplored. Herein, we report a palladium-catalyzed hydrocarbonylative cross-coupling reaction with two different alkenes to produce structurally diverse beta-ketoaldehyde surrogates, which can be easily converted to different types of heterocycles including pyrazole, isoxazole and pyrimidine.
引用
收藏
页码：85 / 89
页数：5
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