Structural Control of Copper-Based MOF Catalysts for Electroreduction of CO2: A Review

被引:1
|
作者
Fu, Hongxin [1 ]
Ma, Hailing [2 ]
Zhao, Shuaifei [3 ]
机构
[1] Shenyang Univ Chem Technol, Coll Sci, Shenyang 110142, Peoples R China
[2] Monash Univ Malaysia, Sch Engn, Subang Jaya 47500, Malaysia
[3] Deakin Univ, Inst Frontier Mat, Geelong, Vic 3216, Australia
关键词
structural control; copper-based MOF catalysts; electroreduction of CO2; CONVERSION; CH4; ACID;
D O I
10.3390/pr12102205
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
With the excessive use of fossil fuels, atmospheric carbon dioxide (CO2) concentrations have risen dramatically in recent decades, leading to serious environmental and social issues linked to global climate change. The emergence of renewable energy sources, such as solar, tidal, and wind energy, has created favorable conditions for large-scale electricity production. Recently, significant attention has been drawn to utilizing renewable energy to catalyze the conversion of CO2 into fuels, producing substantial industrial feedstocks. In these CO2 conversion processes, the structure and performance of catalysts are critical. Metal-organic frameworks (MOFs) and their derivatives have emerged as promising electrocatalysts for CO2 reduction, offering advantages such as high surface area, porosity, exceptional functionality, and high conversion efficiency. This article provides a comprehensive review of structural regulation strategies for copper-based MOFs, highlighting innovative mechanisms like synergistic bimetallic catalysis, targeted doping strategies, and the construction of heterostructures. These novel approaches distinguish this review from previous studies, offering new insights into the electrocatalytic performance of copper-based MOFs and proposing future research directions for improved catalyst design.
引用
收藏
页数:19
相关论文
共 50 条
  • [31] Graphene-Based Catalysts for CO2 Electroreduction
    Du, Yadong
    Meng, Xiangtong
    Wang, Zhen
    Zhao, Xin
    Qiu, Jieshan
    ACTA PHYSICO-CHIMICA SINICA, 2022, 38 (02)
  • [32] CO2 Reduction beyond Copper-Based Catalysts: A Natural Language Processing Review from the Scientific Literature
    Bandeira, Lucas
    Ferreira, Henrique
    Almeida, James Moraes de
    Jardim de Paula, Amauri
    Dalpian, Gustavo Martini
    ACS Sustainable Chemistry and Engineering, 2024, 12 (11): : 4411 - 4422
  • [33] Control of evolution of porous copper-based metal-organic materials for electroreduction of CO2 to multi-carbon products
    Li, Lili
    Shan, Lutong
    Sheveleva, Alena M.
    He, Meng
    Ma, Yujie
    Zhou, Yiqi
    Nikiel, Marek
    Lopez-Odriozola, Laura
    Natrajan, Louise S.
    McInnes, Eric J. L.
    Schroder, Martin
    Yang, Sihai
    Tuna, Floriana
    MATERIALS ADVANCES, 2023, 4 (08): : 1941 - 1948
  • [34] Research progress of electrochemical CO2 reduction for copper-based catalysts to multicarbon products
    Ni, Zhiyuan
    Liang, Haiming
    Yi, Ziyu
    Guo, Rui
    Liu, Chunming
    Liu, Yanguo
    Sun, Hongyu
    Liu, Xuanwen
    COORDINATION CHEMISTRY REVIEWS, 2021, 441
  • [35] Strategies for regulating product selectivity of copper-based catalysts in electrochemical CO2 reduction
    Wang Y.
    Han Z.
    Gao J.
    Wang X.
    Li S.
    Yang Q.
    Weng Z.
    Huagong Jinzhan/Chemical Industry and Engineering Progress, 2023, 42 (08): : 4043 - 4057
  • [36] Strategies to improve the performance of copper-based catalyst for electroreduction of CO2 to multi-carbon products
    Xiang, Kaisong
    Liu, Yucheng
    Yu, Hai
    Liu, Hui
    Li, Kangkang
    CHINESE SCIENCE BULLETIN-CHINESE, 2020, 65 (31): : 3360 - 3372
  • [37] Research progress in copper-based catalysts for methanol synthesis from CO2 hydrogenation
    Zhang, Lijun
    Yang, Haiyan
    Gao, Peng
    Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 2024, 52 (12): : 1759 - 1773
  • [38] Electroreduction of CO2 to Formate on a Copper-Based Electrocatalyst at High Pressures with High Energy Conversion Efficiency
    Li, Jiachen
    Kuang, Yun
    Meng, Yongtao
    Tian, Xin
    Hung, Wei-Hsuan
    Zhang, Xiao
    Li, Aowen
    Xu, Mingquan
    Zhou, Wu
    Ku, Ching-Shun
    Chiang, Ching-Yu
    Zhu, Guanzhou
    Guo, Jinyu
    Sun, Xiaoming
    Dai, Hongjie
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (16) : 7276 - 7282
  • [39] Constructing carbon supported copper-based catalysts for efficient CO2 hydrogenation to methanol
    Xie, Zhong
    Hei, Jinpei
    Li, Chuan
    Yin, Xiaojie
    Wu, Fengyi
    Cheng, Lei
    Meng, Sugang
    RSC ADVANCES, 2023, 13 (21) : 14554 - 14564
  • [40] ON THE ROLE OF ADSORBED ATOMIC OXYGEN AND CO2 IN COPPER-BASED METHANOL SYNTHESIS CATALYSTS
    MUHLER, M
    TORNQVIST, E
    NIELSEN, LP
    CLAUSEN, BS
    TOPSOE, H
    CATALYSIS LETTERS, 1994, 25 (1-2) : 1 - 10