Phototriggered Self-Catalyzed Phosphorylation of 3,4-Dihydroquinoxalin-2(1H)-ones with Diarylphosphine Oxides in EtOH

被引：11
|
作者：
Jiang, Yan-Fang [1 ]
Ouyang, Wen-Tao [1 ]
Ji, Hong-Tao [1 ]
Hou, Jia-Cheng [1 ]
Li, Ting [1 ]
Luo, Qing-Xia [1 ]
Wu, Chao [1 ]
Ou, Li-Juan [2 ]
He, Wei-Min [1 ]
机构：
[1] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China
[2] Hunan Inst Technol, Sch Mat Sci & Engn, Hengyang 421002, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 89卷 / 19期
关键词：
QUINOXALIN-2(1H)-ONES; PHOSPHONATION;
D O I：
10.1021/acs.joc.4c01184
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A highly effective external photocatalyst- and additive-free method for the phosphorylation of 3,4-dihydroquinoxalin-2(1H)-ones to produce phosphorylated dihydroquinoxalin-2(1H)-ones has been reported. A wide variety of phosphorylated products were formed in good to excellent yields. Preliminary mechanistic studies reveal that the phosphorylation process involves an EnT process, a SET process, a HAT process, and a deprotonation process.
引用
收藏
页码：13970 / 13977
页数：8
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