ESR IN TERNARY GdT2Si2 SYSTEMS (T equals Co, Ni, Cu, Ru, Rh, Pd).

被引:0
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作者
Kwapulinska, E. [1 ]
Kaczmarska, K. [1 ]
Szytula, A. [1 ]
机构
[1] Silesian Univ, Katowice, Pol, Silesian Univ, Katowice, Pol
关键词
GADOLINIUM COMPOUNDS - MAGNETISM - Paramagnetism - SPECTROSCOPY; ELECTRON;
D O I
10.1016/0304-8853(88)90169-2
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学科分类号
摘要
ESR spectra of GdT//2Si//2, T equals 3d or 3d metal, have been measured in a paramagnetic state. It was found that g-shift and thermal broadening of the Gd**3** plus resonance line ″b″ depends on the number of d-electrons in the band. The change of the electronic structure of the GdT//2Si//2 compounds, when the different 3d and 4d transition metals are the T-elements, influences visibly ESR spectra. All investigated compounds are bottlenecked systems. The bottleneck effect is stronger as the number of d-electrons in the band increases. The exchange coupling constant between CE and magnetic moments J//S//e is probably positive for GdCu//2Si//2.
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页码:65 / 68
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