REACTION OF OXYGEN AND UNSATURATED FATTY ACIDS.

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Gunstone, F.D.
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ENZYMES AND ENZYME TECHNOLOGY - Applications - ORGANIC COMPOUNDS - Synthesis;
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Oxygen reacts readily with unsaturated fatty acids so that every time these compounds are handled there is a danger they will become contaminated with oxidation products. The products formed first are allylic hydroperoxides which are labile molecules that change rapidly to other compounds, some of which are highly flavorous. Sometimes these changes are desirable and may be promoted: frequently they are not and have to be inhibited.
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