1,2,4-Triazine N-oxides and their annelated derivatives

被引:0
|
作者
Kozhevnikov, D.N. [1 ]
Chupakhin, O.N. [1 ]
机构
[1] Ural State Technical University, ul. Mira 19, 620002 Ekaterinburg, Russia
来源
Russian Chemical Reviews | 1998年 / 67卷 / 08期
关键词
Physical chemistry;
D O I
暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This review deals with the synthesis and properties of 1,2,4-triazine N-oxides and their annelated derivatives. Methods for the incorporation of the N-oxide group in the 1,2,4-triazine ring by direct oxidation and cyclisation involving nitro, nitroso, and isonitroso groups are discussed. Reactions of 1,2,4-triazine N-oxides with electrophiles, nucleophiles, and dicnophilcs are considered. The effect of the N-oxide group on the chemical shifts in the 1H, 13C, and 14N NMR spectra and the specific features of decomposition of 1,2,4-triazine N-oxides under elec-tron impact are analysed. © 1998 Russian Academy of Sciences and Turpion Ltd.
引用
收藏
页码:633 / 648
相关论文
共 50 条
  • [31] MASS SPECTRA OF 1,2,4-TRIAZINE AND SOME OF ITS DERIVATIVES
    PAUDLER, WW
    HERBENER, RE
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 1967, 4 (02) : 224 - &
  • [32] SNII-reactions of 1,2,4-triazine derivatives with acetophenones
    Rusinov, GL
    Itsikson, NA
    Beresnev, DG
    Koryakova, OV
    Chupakhin, ON
    HETEROCYCLIC COMMUNICATIONS, 2002, 8 (01) : 75 - 78
  • [33] Direct arylation and hetarylation of certain 1,2,4-triazine derivatives
    Rusinov, GL
    Beresnev, DG
    Chupakhin, ON
    ZHURNAL ORGANICHESKOI KHIMII, 1998, 34 (03): : 450 - 454
  • [34] Experimental investigation and modeling of the cathodoluminescence of 1,2,4-triazine derivatives
    Tarkhov L.I.
    Potemkin V.A.
    Kozhevnikov D.N.
    Journal of Applied Spectroscopy, 2005, 72 (5) : 636 - 642
  • [35] Ring contraction of 1,2,4-triazine derivatives in the synthesis of imidazoles
    Gazieva, G. A.
    Karpova, T. B.
    Nechaeva, T. V.
    Kravchenko, A. N.
    RUSSIAN CHEMICAL BULLETIN, 2016, 65 (09) : 2172 - 2182
  • [36] Ring contraction of 1,2,4-triazine derivatives in the synthesis of imidazoles
    G. A. Gazieva
    T. B. Karpova
    T. V. Nechaeva
    A. N. Kravchenko
    Russian Chemical Bulletin, 2016, 65 : 2172 - 2182
  • [37] A simple procedure for the synthesis of 1,2,4-triazine 4-oxides
    Yavolovskii, A. A.
    Ivanov, E. I.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2007, 77 (01) : 150 - 150
  • [38] A simple procedure for the synthesis of 1,2,4-triazine 4-oxides
    A. A. Yavolovskii
    E. I. Ivanov
    Russian Journal of General Chemistry, 2007, 77 : 150 - 150
  • [39] NOVEL TRANSFORMATION OF 1,2,4-TRIAZINE RING INTO PYRAZINE DERIVATIVES
    ALEKSEEV, SG
    CHARUSHIN, VN
    CHUPAKHIN, ON
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1987, (02): : 280 - 281
  • [40] A general method for the synthesis of 1,2,4-triazine 4-oxides
    Kozhevnikov, DN
    Kozhevnikov, VN
    Rusinov, VL
    Chupakhin, ON
    MENDELEEV COMMUNICATIONS, 1997, (06) : 238 - 239