Coil-globule transition in star-like macromolecules

被引：0

作者：

Zhulina, Ye.B. ^{[1
]}

Borisov, O.V. ^{[1
]}

Birshtein, T.M. ^{[1
]}

机构：

[1] U.S.S.R. Acad of Sciences, Russia

来源：

Polymer science USSR | 1988年 / 30卷 / 04期

关键词：

Mathematical Models - Solvents;

D O I：

10.1016/0032-3950(88)90189-X

中图分类号：

学科分类号：

摘要：

The conformation was examined in isolated star-like macromolecules in a poor solvent. Asymptotic exponential dependences were derived of equilibrium characteristics of star-like macromolecules (dimensions, density profile of units, conformation free energy). Complete phase diagram was plotted in coordinates of temperature-number of branches. The coil-globule conformation transition was examined in an isolated star-like macromolecule. A formula was derived for the potential of interaction and the second virial coefficient of star-like macromolecules in dilute solution. Experimental data were analysed using the theory formulated.

引用

页码：780 / 788

共 50 条

[41] On gyration radius distributions of star-like macromolecules
Budkov, Yury A.
Kolesnikov, Andrei L.
JOURNAL OF STATISTICAL MECHANICS-THEORY AND EXPERIMENT, 2021, 2021 (06):
[42] DIRECT OBSERVATION OF THE COIL-GLOBULE TRANSITION IN DNA-MOLECULES
MINAGAWA, K
MATSUZAWA, Y
YOSHIKAWA, K
KHOKHLOV, AR
DOI, M
BIOPOLYMERS, 1994, 34 (04) : 555 - 558
[43] Coil-globule transition of poly(methyl methacrylate) by intrinsic viscosity
J Chem Phys, 19 (8701):
[44] Finite chain length effects on the coil-globule transition of stiff-chain macromolecules: A Monte Carlo simulation
Ivanov, VA
Paul, W
Binder, K
JOURNAL OF CHEMICAL PHYSICS, 1998, 109 (13): : 5659 - 5669
[45] Coil-globule transition of a single semiflexible chain in slitlike confinement
Dai, Liang
Renner, C. Benjamin
Yan, Jie
Doyle, Patrick S.
SCIENTIFIC REPORTS, 2015, 5
[46] Coil-globule transition of poly(methyl methacrylate) by intrinsic viscosity
Baysal, BM
Kayaman, N
JOURNAL OF CHEMICAL PHYSICS, 1998, 109 (19): : 8701 - 8707
[47] Coil-globule transition of poly(methyl methacrylate) in isoamyl acetate
Nakata, M
Nakagawa, T
PHYSICAL REVIEW E, 1997, 56 (03): : 3338 - 3345
[48] "Raindrop" Coalescence of Polymer Chains during Coil-Globule Transition
Lappala, Anna
Terentjev, Eugene M.
MACROMOLECULES, 2013, 46 (03) : 1239 - 1247
[49] INTRAMOLECULAR CONFORMATIONAL TRANSFER OF THE COIL-GLOBULE TYPE IN MACROMOLECULES OF LIQUID-CRYSTALLINE POLYMERS
FREIDZON, JS
SHIBAEV, VP
PAUTOV, VD
BRONICH, TK
SHELUKHINA, GD
KASAIKIN, VA
PLATE, NA
DOKLADY AKADEMII NAUK SSSR, 1981, 256 (06): : 1435 - 1438
[50] Scaled Particle Theory for the Coil-Globule Transition of an Isolated Polymer Chain
Simmons, David S.
Sanchez, Isaac C.
MACROMOLECULES, 2013, 46 (11) : 4691 - 4697

← 1 2 3 4 5 →