RAIRS observation of photoinduced dissociation of NO on Ni(111)

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Univ of Tokyo, Tokyo, Japan [1 ]
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Surf Sci | / 2卷 / L669-L672期
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Absorption spectroscopy - Adsorption - Dissociation - Infrared spectroscopy - Laser beam effects - Molecular vibrations - Nitrogen oxides - Photochemical reactions - Surfaces - Ultraviolet radiation;
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摘要：
The properties of the NO/Ni(111) system under nanosecond ultraviolet laser light irradiation are studied by reflection absorption infrared spectroscopy. It is found that adsorbed NO molecules are dissociated by laser light. Dissociation proceeds effectively in a dilute NO layer, whereas it is suppressed in a saturated overlayer.
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