Principles of thermodynamics of condensation on soluble nuclei of surface - active substances

被引：0
|
作者：
Rusanov, A.I. [1 ]
Kuni, F.M. [1 ]
Shchekin, A.K. [1 ]
机构：
[1] Gosudarstvennyj Univ, St. Petersburg, Russia
来源：
Kolloidnyj Zhurnal | 1993年 / 55卷 / 02期
关键词：
Adsorption - Liquids - Phase transitions - Surface active agents - Thermodynamics - Vapors;
D O I：
暂无
中图分类号：
TK1 [热力工程、热机];
学科分类号：
080702 ;
摘要：
Condensation on soluble nuclei has been considered taking into account the adsorption of nucleus substance at the drop surface. Nucleation thermodynamics has been investigated for the case of the strong adsorption unsaturation. Principles of thermodynamics of condensation on a soluble nuclei have been formulated for the case arbitrary degree of adsorption saturation. A general thermodynamic expression for extreme value of the chemical potential of condensate was found. Closed system of equations connecting thermodynamic characteristics of the drop having the extreme value of condensate chemical potential was derived. The limiting case of complete saturation of adsorption has been considered.
引用
收藏
页码：55 / 63
相关论文
共 50 条
  • [41] SURFACE PHENOMENA AND SURFACE-ACTIVE SUBSTANCES
    RUSANOV, AI
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1990, 39 (12): : 2427 - 2437
  • [42] CALCULATION AND ANALYSIS OF THERMODYNAMIC CHARACTERISTICS FOR THE CONDENSATION KINETICS ON THE SOLUBLE NUCLEI OF A SURFACTANT
    SHCHEKIN, AK
    KUNI, FM
    YAKOVENKO, TM
    RUSANOV, AI
    COLLOID JOURNAL, 1995, 57 (02) : 242 - 248
  • [43] Calculation and analysis of thermodynamic characteristics of condensation kinetics on the soluble surfactant nuclei
    Shchekin, A.K.
    Kuni, F.M.
    Yakovenko, T.M.
    Rusanov, A.I.
    Kolloidnyj Zhurnal, 1995, 57 (02): : 261 - 267
  • [44] The adsorption of water soluble substances and active carbon.
    Skumburdis, K
    KOLLOID-ZEITSCHRIFT, 1928, 44 (02): : 127 - 133
  • [45] Chiral symmetry and surface pion condensation in nuclei and hypernuclei
    Toki, H
    Ogawa, Y
    Tamenaga, S
    Ikeda, K
    Sugimoto, S
    ELECTROPHOTOPRODUCTION OF STRANGENESS ON NUCLEONS AND NUCLEI, 2004, : 119 - 134
  • [46] PRINCIPLES OF SEARCHES FOR NEW PHARMACOLOGICALLY ACTIVE SUBSTANCES TODAY
    MASHKOVSKY, MD
    VESTNIK AKADEMII MEDITSINSKIKH NAUK SSSR, 1982, (05): : 9 - 14
  • [47] Thermodynamics of droplet formation around a soluble condensation nucleus in the atmosphere of a solvent vapor
    Shchekin, A. K.
    Shabaev, I. V.
    Rusanov, A. I.
    JOURNAL OF CHEMICAL PHYSICS, 2008, 129 (21):
  • [48] Surface active substances in the Eastern Mediterranean
    Cosovic, B
    Ciglenecki, I
    CROATICA CHEMICA ACTA, 1997, 70 (01) : 361 - 371
  • [49] SURFACE-ACTIVE SUBSTANCES IN TEARS
    BOGART, BI
    LEW, G
    OCONNOR, P
    SACK, R
    INVESTIGATIVE OPHTHALMOLOGY & VISUAL SCIENCE, 1993, 34 (04) : 1469 - 1469
  • [50] SURFACE-ACTIVE SUBSTANCES AND ANTIBIOTICS
    FIELDING, J
    LANCET, 1949, 256 (JAN15): : 121 - 122
12345