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- [43] An efficient synthesis of 12-vertex closo-rhodacarboranes [3-(η5-C5Me5)-1-R1-2-R2-3,1,2-closo-RhC2B9H9] (R1, R2 = H, Alk) via two-step reactions of [K][7-R1-8-R2-7,8-nido-C2B9H10] mono-anions with [Rh2(η5-C5Me5)2Cl4]:: structural characterization of the first purely closo-type metallacarborane with sterically demanding C,C′-dibenzylsubstituted carborane ligand JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2008, 693 (21-22) : 3331 - 3336