Determination of the Sb activity in Sb-Te melts by solid state EMF measurements

被引：0
|
作者：
Feutelais, Y. [1 ]
Legendre, B. [1 ]
Misra, S. [1 ]
Anderson, T.J. [1 ]
机构：
[1] Faculte de Pharmacie, France
来源：
Journal of Phase Equilibria | 1994年 / 15卷 / 02期
关键词：
Binary alloys - Composition - Electrochemical electrodes - Electrolytes - Liquid metals - Solubility - Zirconia;
D O I：
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中图分类号：
学科分类号：
摘要：
The antimony activity in liquid Sb-Te solutions was measured at 911 K using a solid-state galvanic cell. The measurements indicated nearly ideal solution behavior for Sb-rich compositions and moderate negative deviations for Te-rich compositions (NTe > 0.45), consistent with the presence of short-range order in the melt. The results of this study were shown to be in good agreement with other thermochemical property values for this binary system.
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页码：171 / 177
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