ORGANOMETALLIC POLYMERS.

被引：0

作者：

Pittman, Charles U. ^{[1
]}

Rausch, Marvin D. ^{[1
]}

机构：

[1] Mississippi State Univ, Mississippi,, MS, USA, Mississippi State Univ, Mississippi, MS, USA

来源：

Pure and Applied Chemistry | 1985年 / 58卷 / 04期

关键词：

IRON COMPOUNDS - Synthesis - MONOMERS - Chemical Reactions - POLYMERIZATION - Copolymerization - POLYMERS - Molecular Structure - VINYL RESINS - Reactions;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The homopolymerization kinetics of ( eta **5-vinylCp)W(CO)//3CH//3 and ( eta **5-vinylCp)Cr(CO)//2NO were studied. Copolymerization of several eta **5-vinylCp monomers with styrene, methyl acrylate, acrylonitrile and N-vinylpyrrolidone were conducted using radical initiation. From the reactivity ratios, values of the Alfrey-Price Qe parameters were obtained, illustrating that all of the metallic monomers studied were exceptionally electron rich. Cationic initiation of the ( eta **5-isopropenylCp)-metal type monomers gave low molecular weight homopolymers and copolymers at best. The syntheses of 1,1 prime -bis( beta -aminoethyl)ferrocene and their interfacial polycondensation with both diacid chlorides and diisocyanates was conducted.

引用

页码：617 / 622

共 50 条

[31] SEMICONDUCTING POLYMERS.
Hermann, A.M.
1600, (03): : 1 - 2
[32] Cell interactive polymers.
Mooney, DJ
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U547 - U547
[33] Organometallic nonlinear optical (NLO) polymers. Further development of pendent ferrocene poly(methyl methacrylate) copolymers
Wright, M.E.
Toplikar, E.G.
Polymer Preprints, Division of Polymer Chemistry, American Chemical Society, 1993, 34 (01):
[34] Aldehyde plasma polymers.
Beumer, GJ
Gong, X
Dai, L
StJohn, HAW
Griesser, HJ
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 213 : 460 - POLY
[35] Photophysics of semiconducting polymers.
Heeger, AJ
Moses, D
Miranda, P
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 222 : U287 - U287
[36] ELECTRICALLY CONDUCTING POLYMERS.
Gill, W.D.
Clarke, T.C.
Street, G.B.
Applied physics communications, 1982, 2 (04): : 211 - 282
[37] Microthermal characterisation of polymers.
Reading, M
Price, DM
Grandy, D
Pollock, HM
Hammiche, A
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 220 : U249 - U249
[38] Design of sensory polymers.
Swager, TM
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 217 : U482 - U482
[39] CONTROLLED AUTOXIDATION OF POLYMERS.
Scott, G.
1600,
[40] Rheology and the Processing of Polymers.
Wippler, C.
1978, 55 (582): : 79 - 85

← 1 2 3 4 5 →