Mixed micellar properties of octyl-β-D-glucoside and lithium perfluorooctane sulfonate

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Department of Applied Chemistry, Inst. of Colloid and Interface Sci., Science University of Tokyo, Kagurazaka, Shinjuku-ku, Tokyo 162, Japan [1 ]
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COLLOIDS SURF. A PHYSICOCHEM. ENG. ASP. | / 3卷 / 231-234期
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Binary mixtures - Fluorocarbons - Hydrocarbons - Micelles - Mixing - Physical properties - Sugars;
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摘要：
Mixed micellar properties of octyl-β-D-glucoside (AG8) and lithium perfluorooctane sulfonate in aqueous solution have been studied. The mixture CMC values are lower than data for ideal mixing, indicating that a favorable interaction in the mixed micelles arises, having the interaction parameter -1.85. The aggregation number of mixed micelles increases gradually until the mole fraction of AG8=0.8 and then increases sharply. A similar change is observed for the micellar radius. Thus, the micellar properties of mixed micelles are markedly affected by incorporation of the fluorocarbon surfactant.
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