Electrochemically lithiated vanadium oxide, Li2V6O13

被引：0

作者：

Uppsala Univ, Uppsala, Sweden ^{[1
]}

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来源：

Acta Crystallographica, Section C: Crystal Structure Communications | 1997年 / 53卷 / pt 5期

关键词：

Crystal growth - Crystal structure - Electrochemistry - Lithium - Single crystals;

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摘要：

Single crystals of V6O13 were grown by chemical vapour transport and then electrochemically lithiated. The title compound, dilithium hexavanadium tridecaoxide, was the first phase formed during electrochemical lithiation at 2.65 V versus Li/Li+. The Li2V6O13 structure can be described as layers of VO6 octahedra stacked perpendicular to the c direction. Lithiation causes a 7.6% expansion along the c axis. The lithium ions occupy positions with fivefold square-pyramidal oxygen coordination between the layers.

引用

页码：528 / 530

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