Kinetics of wet oxidation of formic acid and acetic acid

Oxidation of lower molecular weight carboxylic acids such as formic, acetic, glyoxalic, and oxalic acids is often the rate-controlling step during wet oxidation (WO) of an aqueous waste stream exhibiting very high chemical oxygen demand (COD). The kinetics of WO of formic acid was studied in the absence and presence of a cupric sulfate as catalyst in the temperature range 150-240 °C and oxygen partial pressure range 0.345-1.380 MPa. Wet oxidation of acetic acid was carried out in the presence of cupric sulfate in the temperature range 215-235 °C. Homogeneous copper sulfate was found to be a very good catalyst for oxidation of formic acid and acetic acid.