Topochemical polymerization of 1-naphthyl-methylammonium muconate and sorbate as the (E,E)-diene monomers in the crystalline state

被引：0

作者：

Matsumoto, Akikazu ^{[1
]}

Odani, Toru ^{[1
]}

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Osaka City University, Sumiyoshi-ku, Osaka, 558-8585, Japan

来源：

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry | 1999年 / 40卷 / 02期

关键词：

Aromatic polymers - Carboxylic acids - Crystalline materials - Molecular crystals - Molecular structure - Monomers - Nuclear magnetic resonance spectroscopy - Photochemical reactions - Polymerization - Stereochemistry - Synthesis (chemical) - X ray powder diffraction;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Topochemical polymerization of the (E,E)-diene derivative was demonstrated. The 1-naphthylmethylammonium salt of (E,E)-muconic and sorbic acids polymerized in the crystalline state and provided a stereoregular polymer. NMR spectra of the resulting muconate polymers showed a meso-diisotactic-trans-2-5-structure, irrespective of the configurations of the monomers. On the other hand, based on powder X-ray diffraction profiles, during topochemical polymerization, the mode and rate of the reactions are determined by the molecular packing of the substrates, suggesting that geometrical isomers should be regarded as completely different compounds rather than homologous monomers.

引用

页码：305 / 306

共 29 条

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