Topochemical polymerization of 1-naphthyl-methylammonium muconate and sorbate as the (E,E)-diene monomers in the crystalline state

被引：0

作者：

Matsumoto, Akikazu ^{[1
]}

Odani, Toru ^{[1
]}

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Osaka City University, Sumiyoshi-ku, Osaka, 558-8585, Japan

来源：

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry | 1999年 / 40卷 / 02期

关键词：

Aromatic polymers - Carboxylic acids - Crystalline materials - Molecular crystals - Molecular structure - Monomers - Nuclear magnetic resonance spectroscopy - Photochemical reactions - Polymerization - Stereochemistry - Synthesis (chemical) - X ray powder diffraction;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Topochemical polymerization of the (E,E)-diene derivative was demonstrated. The 1-naphthylmethylammonium salt of (E,E)-muconic and sorbic acids polymerized in the crystalline state and provided a stereoregular polymer. NMR spectra of the resulting muconate polymers showed a meso-diisotactic-trans-2-5-structure, irrespective of the configurations of the monomers. On the other hand, based on powder X-ray diffraction profiles, during topochemical polymerization, the mode and rate of the reactions are determined by the molecular packing of the substrates, suggesting that geometrical isomers should be regarded as completely different compounds rather than homologous monomers.

引用

页码：305 / 306

共 29 条

[1] Topochemical polymerization of 1-naphthylmethylammonium muconate and sorbate as the (E,E)-diene monomers in the crystalline state.
Matsumoto, A
Odani, T
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 218 : U402 - U402
[2] Topochemical polymerization of diene monomers in the crystalline state to control the stereochemistry of the polymers
Matsumoto, Akikazu
Odani, Toru
ACS Symposium Series, 2000, 768 : 93 - 106
[3] Stereospecific polymerization of 1,3-diene monomers in the crystalline state
Matsumoto, A
PROGRESS IN REACTION KINETICS AND MECHANISM, 2001, 26 (01) : 59 - 109
[4] Thermally induced topochemical polymerization of 1,3-diene monomers
Nagahama, S
Matsumoto, A
CHEMISTRY LETTERS, 2002, (10) : 1026 - 1027
[5] 5Å rule for the topochemical polymerization of 1,3-diene monomers.
Odani, T
Nagahama, S
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U436 - U436
[6] Topochemical polymerization of 1,3-diene monomers and features of polymer crystals as organic intercalation materials
Matsumoto, A
Odani, T
MACROMOLECULAR RAPID COMMUNICATIONS, 2001, 22 (15) : 1195 - 1215
[7] Photodimerization mechanism of bis(3,4,5-trifluorobenzyl) (E,E)-muconate in a columnar assembly in the crystalline state
Mori, Yutaka
Matsumoto, Akikazu
CHEMISTRY LETTERS, 2007, 36 (04) : 510 - 511
[8] TOPOCHEMICAL REACTIONS OF MONOMERS WITH CONJUGATED TRIPLE BONDS .I. POLYMERIZATION OF 2.4-HEXADIYN-1.6-DIOLS DEIVATIVES IN CRYSTALLINE STATE
WEGNER, G
ZEITSCHRIFT FUR NATURFORSCHUNG PART B-CHEMIE BIOCHEMIE BIOPHYSIK BIOLOGIE UND VERWANDTEN GEBIETE, 1969, B 24 (07): : 824 - &
[9] Two-dimensional hydrogen bond networks supported by CH/π interaction leading to a molecular packing appropriate for topochemical polymerization of 1,3-diene monomers
Nagahama, S
Inoue, K
Sada, K
Miyata, M
Matsumoto, A
CRYSTAL GROWTH & DESIGN, 2003, 3 (02) : 247 - 256
[10] MOLECULAR CONFORMATION OF 1E,2A,6E-TRIMETHYL-4E-PHENYL-4A-ACETOXYPIPERIDINE HYDROBROMIDE IN CRYSTALLINE STATE
HAYAKAWA, K
JAMES, MNG
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1973, 51 (10): : 1535 - 1542

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