Two-dimensional molecular arrangement in phthalocyanine based conducting crystals

被引：0
|
作者：
Inabe, Tamotsu [1 ]
Morimoto, Kazuhiro [1 ]
Hasegawa, Hiroyuki [1 ]
Miyajima, Nobuhiko [1 ]
机构：
[1] Hokkaido Univ, Sapporo, Japan
来源：
Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals | 1996年 / 278-279卷 / pt 3-4期
关键词：
Cobalt compounds - Conductive materials - Crystals - Ions - Molecular structure - Oxidation - Potassium compounds - Three dimensional;
D O I：
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学科分类号：
摘要：
Molecular arrangements in the crystals composed of the dicyanocobalt(III)phthalocyanine units, Co(Pc)(CN)2, have been examined. When the unit is closed-shell anion, the crystals contain one-dimensional arrays or isolated dimers of the Co(Pc)(CN)2 units. Two-dimensional sheets of Co(Pc)(CN)2, which are similar to those observed for the partially oxidized potassium salt, are formed when the unit is completely oxidized with existence of chloroform. A three-dimensional network of Co(Pc)(CN)2 is also obtained when the unit is oxidized with existence of water. Resultant neutral radical crystals, Co(Pc)(CN)2.2CHCl3 and Co(Pc)(CN)2.2H2O, are highly conducting.
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页码：151 / 156
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