(4,4′-bipyridine)dichloromanganese(II), a two-dimensional coordination polymer

被引:0
|
作者
Chippindale, Ann M. [1 ]
Cowley, Andrew R. [2 ]
Peacock, Katherine J. [2 ]
机构
[1] Department of Chemistry, University of Reading, Whiteknights, Reading RG6 6AD, United Kingdom
[2] Chemical Crystallography Laboratory, 9 Parks Road, Oxford OX1 3PD, United Kingdom
关键词
Chemical bonds - Chlorine compounds - Crystal atomic structure - Crystal symmetry - Crystallization - Manganese compounds - Molecular structure - Single crystals;
D O I
10.1107/S0108270100003474
中图分类号
学科分类号
摘要
The title compound, [MnCl2(C10H8N2)]n, crystallizes with a two-dimensional network constructed from linear chains of edge-sharing MnCl4 square-planar units cross-linked by bidentate 4,4′-bipyridine bridges. The Mn atom and the bipyridine moieties lie on sites with 222 crystallographic symmetry; the Cl atom lies on a twofold axis. The bipyridine molecule is twisted about the central C-C bond by 33.5 (3)°.
引用
收藏
页码:651 / 652
相关论文
共 50 条
  • [41] Monomers, chains, ladders, and two-dimensional sheets:: Structural diversity in six new compounds of Zn(II) with 4,4′-bipyridine
    Woodward, Jonathan D.
    Backov, Renal V.
    Abboud, Khalil A.
    Talham, Daniel R.
    POLYHEDRON, 2006, 25 (13) : 2605 - 2615
  • [42] A threefold interpenetrated two-dimensional zinc(II) supramolecular architecture based on 3-nitrobenzoic acid and 4,4′-bipyridine
    Tang, Long
    Wang, Ji-Jiang
    Fu, Feng
    Wang, Sheng-Wen
    Liu, Qi-Rui
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2016, 72 : 128 - +
  • [43] Synthesis and crystal structure of a 6-chloronicotinate salt of a one-dimensional cationic nickel(II) coordination polymer with 4,4′-bipyridine
    Politeo, Nives
    Pisacic, Mateja
    Dakovic, Marijana
    Sokol, Vesna
    Kukovec, Boris-Marko
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2020, 76 : 599 - +
  • [44] A Two-Dimensional Coordination Polymer Based on 1,1′:4′, 1"-Terphenyl-2′,4,4",5′-tetracarboxylate
    Yin, Xiu-Ju
    Fu, Yong
    CRYSTALLOGRAPHY REPORTS, 2018, 63 (03) : 401 - 404
  • [45] Synthesis, Crystal Structure and Fluorescence Characterization of Cadmium(II) Coordination Polymer with 4-Acetamidobenzoic Acid and 4,4′-Bipyridine
    Yang Ying-Qun
    Li Chang-Hong
    Li Wei
    Yi Zheng-Ji
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2009, 25 (07) : 1304 - 1307
  • [46] A Two-Dimensional Coordination Polymer Based on 1,1':4',1''-Terphenyl-2',4,4'',5'-tetracarboxylate
    Xiu-Ju Yin
    Yong Fu
    Crystallography Reports, 2018, 63 : 401 - 404
  • [47] Zinc(II) coordination polymer with 4,4′-quinoline ligand
    Wang Wei
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2007, 23 (07) : 1306 - 1308
  • [48] Lead(II) coordination polymer with 4,4′-biquinoline ligand
    Wang Wei
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2007, 23 (06) : 1040 - 1044
  • [50] Syntheses and characterizations of two copper coordination polymers constructed by 4,4′-bipyridine
    Zhang, J
    Li, ZJ
    Qin, YY
    Wen, YH
    Kang, Y
    Yao, YG
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (12) : 1366 - 1370