(4,4′-bipyridine)dichloromanganese(II), a two-dimensional coordination polymer

被引：0
|
作者：
Chippindale, Ann M. [1 ]
Cowley, Andrew R. [2 ]
Peacock, Katherine J. [2 ]
机构：
[1] Department of Chemistry, University of Reading, Whiteknights, Reading RG6 6AD, United Kingdom
[2] Chemical Crystallography Laboratory, 9 Parks Road, Oxford OX1 3PD, United Kingdom
来源：
Acta Crystallographica, Section C: Crystal Structure Communications | 2000年 / 56卷 / 06期
关键词：
Chemical bonds - Chlorine compounds - Crystal atomic structure - Crystal symmetry - Crystallization - Manganese compounds - Molecular structure - Single crystals;
D O I：
10.1107/S0108270100003474
中图分类号：
学科分类号：
摘要：
The title compound, [MnCl2(C10H8N2)]n, crystallizes with a two-dimensional network constructed from linear chains of edge-sharing MnCl4 square-planar units cross-linked by bidentate 4,4′-bipyridine bridges. The Mn atom and the bipyridine moieties lie on sites with 222 crystallographic symmetry; the Cl atom lies on a twofold axis. The bipyridine molecule is twisted about the central C-C bond by 33.5 (3)°.
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页码：651 / 652
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