On formation of carbin (cyanopolyine) and diamond in Fe-C alloys

被引:0
|
作者
Savulyak, V.I. [1 ]
Zhukov, A.A. [1 ]
机构
[1] Vinnitskij GTU, Vinnitsa, Ukraine
关键词
Carbon - Cast iron - Chemical bonds - Diamonds - Graphite - Iron alloys - Pressure control - Steel - Synthesis (chemical) - Temperature control;
D O I
暂无
中图分类号
学科分类号
摘要
A problem of formation of carbin (cyanopolyine) as the 'linear' allotropic modification of crystalline carbon in Fe-C alloys (U8 steel, cast irons) is discussed. The cases of diamond crystals forming in solidifying austenitic cast iron are considered. Authors think that the small amount of carbin can be present in the cast iron austenitic phase (in axial zone of graphite branching). It is inferred that the Fe3C&rarr3Fe+C (diamond) reaction is possible at atmospheric pressure only over certain temperature range in which accem>acdiam (a - carbon activity).
引用
收藏
页码:37 / 40
相关论文
共 50 条
  • [21] Formation of θ-Fe3C Cementite via θ′-Fe3C (ω-Fe3C) in Fe-C Alloys
    Ping, De-hai
    Chen, Hao
    Xiang, Hongping
    CRYSTAL GROWTH & DESIGN, 2021, 21 (03) : 1683 - 1688
  • [22] Thermodynamics of bainitic formation in carbon-depleted region in Fe-C alloys
    Wu, Xiaolei
    Meng, Xiangkang
    Zhang, Xiyan
    Yang, Yanqing
    Kang, Mokuang
    Journal of Materials Science and Technology, 1994, 10 (06): : 441 - 444
  • [23] Simulation of the peritectic reaction in Fe-C alloys
    Hillert, M
    Höglund, L
    MATERIALS TRANSACTIONS JIM, 1999, 40 (06): : 564 - 566
  • [24] DISLOCATION STRUCTURES IN FATIGUED FE-C ALLOYS
    MCGRATH, JT
    BRATINA, WJ
    JOURNAL OF METALS, 1965, 17 (09): : 1032 - &
  • [25] SOME PROBLEMS OF DECARBURIZATION OF FE-C ALLOYS
    SEMENOV, NP
    YAVOISKI.VI
    HEINEMAN, AV
    STEEL IN THE USSR, 1972, 2 (03): : 193 - &
  • [26] INFLUENCE OF SILICON OF PROPERTY OF FE-C ALLOYS
    GALPERIN, FM
    AMELIN, II
    ERKIN, VM
    SALUGIN, AN
    FILIN, MV
    KHRAPOV, AY
    MARKS, GL
    PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1974, 21 (02): : K85 - K87
  • [27] REPEATED YIELDING IN QUENCHED FE-C ALLOYS
    BRATINA, WJ
    MCGRATH, JT
    MILLS, D
    TRANSACTIONS OF THE JAPAN INSTITUTE OF METALS, 1968, S 9 : 436 - &
  • [28] MICROSEGREGATION IN FE-C ALLOYS OF FUSED TYPE
    CHARBONNIER, J
    MARGERIF, JC
    MEMOIRES SCIENTIFIQUES DE LA REVUE DE METALLURGIE, 1968, 65 (7-8): : 603 - +
  • [29] The atomic structure of liquid Fe-C alloys
    Pan, Shaopeng
    Feng, Shidong
    Qiao, Junwei
    Dong, Bangshao
    Qin, Jingyu
    JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 648 : 178 - 183
  • [30] Numerical modelling of Fe-C alloys crystallization
    Majchrzak, E
    Piasecka, A
    ADVANCED COMPUTATIONAL METHODS IN HEAT TRANSFER IV, 1996, : 621 - 630