Synthesis and characterization of Bromo- and bromochloroplumbates(II). Crystal structures of [Ph4E]2[Pb3Br8] (E = P, As) and [Ph4P][PbBrCl2] · CH3CN

被引：0

作者：

Klapötke, Thomas M. ^{[1
]}

Krumm, Burkhard ^{[1
]}

Polborn, Kurt ^{[1
]}

Rienäcker, Claudia M. ^{[1
]}

机构：

[1] Department Chemie, Ludwig-Maximilians-Univ. Munchen, Butenandtstr. 5-13 (D), D-81377 München, Germany

来源：

Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences | 2000年 / 55卷 / 05期

关键词：

Quantum chemistry;

D O I：

10.1515/znb-2000-0506

中图分类号：

学科分类号：

摘要：

[Ph4P]2[Pb3Br8] and [Ph4As]2[Pb3Br8] crystallize both in the monoclinic space group P 21/n. The lattice parameters of [Ph4P]2[Pb3Br8] are a = 14.637(7), b = 8.151(3), c = 23.388(8) Å, β = 106.02(3)°, Z = 2 and of [Ph4As]2[Pb3Br8] are a = 14.697(7), b = 8.219(3), c = 23.527(8) Å, β = 106.27(3)°, Z = 2. The lattice parameters of [Ph4P][PbBrCl2]·CH3CN, which crystallizes in the triclinic space group (P 1¯), are a = 9.435(3), b = 10.2577(14), c = 14.055(2) Å, α = 88.320(11)°, β = 84.82(2)°, γ = 84.19(2)°, Z = 2. 207Pb NMR shifts of halogenoplumbates in solution are reported.

引用

页码：377 / 382

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