31P NUCLEAR MAGNETIC RESONANCE STUDY OF LOCAL BONDING CONFIGURATION OF PHOSPHORUS IN AMORPHOUS SILICON-HYDROGEN-PHOSPHORUS ALLOYS.

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作者
Hayashi, Shigenobu [1 ]
Hayamizu, Kikuko [1 ]
Yamasaki, Satoshi [1 ]
Matsuda, Akihisa [1 ]
Tanaka, Hazunobu [1 ]
机构
[1] Natl Chemical Lab for Industry, Tsukuba, Jpn, Natl Chemical Lab for Industry, Tsukuba, Jpn
关键词
HYDROGEN - NUCLEAR MAGNETIC RESONANCE - PHOSPHORUS;
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摘要
**3**1P nuclear magnetic resonance (NMR) spectra have been measured for amorphous hydrogenated silicon heavily doped with phosphorus. Phosphorus is enriched in the film during glow-discharge decomposition of the SiH//4-PH//3 mixture at a substrate temperature of 250 degree C by a factor of 3. **3**1P NMR results demonstrate that almost all the phosphorus atoms are bonded to three silicon atoms, and not to hydrogen or to other phosphorus.
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页码:2041 / 2043
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