The chemical and thermal criteria used for predicting the spontaneous combustion hazard are reviewed and data are presented to characterize the gas desorptions and self-heating tendencies of 29 U. S. coals. CO, CO//2, and CH//4 are the main gases evolved and the CO, CO/ DELTA O//2 index, and O//2 absorption rate increase with decreasing rank and increasing oxygen content. The presence of CO alone is not necessarily an indication of a self-heating reaction of the coal.